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Chelsea matches where Frank Rijkaard was opposition manager/coach
| Date | Venue | Opponent | Score | Comp |
| 23/02/2005 | Nou Camp | Barcelona | 1-2 | UEFA Champions League |
| 08/03/2005 | Stamford Bridge | Barcelona | 4-2 | UEFA Champions League |
| 22/02/2006 | Stamford Bridge | Barcelona | 1-2 | UEFA Champions League |
| 07/03/2006 | Nou Camp | Barcelona | 1-1 | UEFA Champions League |
| 18/10/2006 | Stamford Bridge | Barcelona | 1-0 | UEFA Champions League |
| 31/10/2006 | Nou Camp | Barcelona | 2-2 | UEFA Champions League |